TA Instruments

25% SIH 75% PCHINA-0029f

29/04/2022 5:00:25 p. m.

Sample name	25% SIH 75% PCHINA
Sample notes	 
Experiment notes	
Operator	
Sample density	1,000 g/cm^3
Results file name	25% SIH 75% PCHINA
Run number	29 
Results directory	C:\Ta\Data\Ar1500\Ar1500\DIEGO ROA
Experiment was run on	29/04/2022 5:00:25 p. m.

Procedure name	Flow procedure
Procedure notes	

Step name	Conditioning Step 1
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	No
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Stepped flow step 1
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000E-3 1/s
End controlled variable	shear rate 0,01000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 2
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,01000 1/s
End controlled variable	shear rate 0,1000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 3
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,1000 1/s
End controlled variable	shear rate 1,000 1/s
Ramp mode	log 
Points per decade	5 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 4
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000 1/s
End controlled variable	shear rate 100,0 1/s
Ramp mode	log 
Points per decade	8 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Conditioning Step 2
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	Yes
Pre-shear variable	10,00 1/s
Pre-shear duration	0:00:10 hh:mm:ss
Motor mode	auto 
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Temperature ramp step 1
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	25,0 C
End temperature	90,0 C
Wait for start temperature	Yes
Ramp rate	10,00 C/min
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Temperature ramp step 2
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	90,0 C
End temperature	90,0 C
Wait for start temperature	No
Ramp duration	0:05:00 hh:mm:ss
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Temperature ramp step 3
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	90,0 C
End temperature	25,0 C
Wait for start temperature	No
Ramp rate	10,00 C/min
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Conditioning Step 3
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	Yes
Pre-shear variable	1,000 1/s
Pre-shear duration	0:00:10 hh:mm:ss
Motor mode	auto 
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Stepped flow step 5
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000E-3 1/s
End controlled variable	shear rate 0,01000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 6
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,01000 1/s
End controlled variable	shear rate 0,1000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 7
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,1000 1/s
End controlled variable	shear rate 1,000 1/s
Ramp mode	log 
Points per decade	5 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 8
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000 1/s
End controlled variable	shear rate 100,0 1/s
Ramp mode	log 
Points per decade	8 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Post-Experiment Step
Step notes	
Perform step	Yes
Do set temperature	No
Set temperature system idle	No

Geometry name	Starch cell
Geometry notes	Starch cell
Geometry material	High temperature
gap	5500 micro m
Calibration factor	10800 
Gap offset	0 micro m
Geometry inertia	2,224 micro N.m.s^2
Shear rate factor	1,000 
Shear stress factor	10800 1/m^3
Measurement system factor	10800 1/m^3
Fluid density factor	1,000E-15 m^5
Normal force factor	1,000 1/m^2
Backoff distance	1,25E5 micro m

Gap zero mode	Standard
Sample compression	none 
Compression distance	1000,0 micro m
Compression velocity	100,0 micro m/s
Fine velocity	1000,0 micro m/s
Coarse velocity	3000,0 micro m/s
Other velocity	3000,0 micro m/s
Current temperature system	Starch cell
Temperature control	Enabled 
Purge gas only	No
Temperature calibration	Peltier plate - 0 micro m/C
	Water bath - 0 micro m/C
	Torsion oven - plate - 0 micro m/C
	Torsion oven - solid sample - 0 micro m/C
	Peltier concentric cylinders - 0 micro m/C
	None - 0 micro m/C
	Stress relaxation - 0 micro m/C
	Current temperature system - 0 micro m/C
Cooling water temperature	5,0 C
Cooling water range	15,0 C
Bearing friction correction	Yes
Bearing friction	1,222 micro N.m/(rad/s)
Bearing offset	0 micro N.m
Temperature system span and offset	Peltier plate - span 1,0000 , offset 0 C
	Water bath - span 1,0000 , offset 0 C
	Torsion oven - plate - span 1,0000 , offset 0 C
	Torsion oven - solid sample - span 1,0000 , offset 0 C
	Peltier concentric cylinders - span 1,0000 , offset 0 C
	None - span 1,0000 , offset 0 C
	Stress relaxation - span 1,0000 , offset 0 C
	Current temperature system - span 1,0000 , offset 0 C
Bearing mapping type	fast 
Number of mapping iterations	1
Instrument type (MType)	AR1500ex
Firmware version	  8.29  27/10/09
Configuration version (CnfVer)	301
Parameter version (PrmVer)	301
PCB Number	*NOT_SET*
IP address	172.23.191.2
Software version	V5.8.2
Windows version	Windows XP 6.2
Instrument inertia	15,97 micro N.m.s^2
Auto increment run number	Yes
Prompt for file name at start of run	Yes
Auto save results file	Yes
Results file storage	Consecutive steps of same type to 1 file 
Temperature tolerance	0,2 C
Temperature duration	0:00:10 hh:mm:ss
Wait for temperature even if OK	Yes
Gap tolerance	4 micro m
Gap duration	0:00:02 hh:mm:ss
Override wait for gap	No
Velocity tolerance	0,1000 rad/s
Zero speed after pre-shear	Leave as is 
Zero normal force before run	No
Zero timer before run	Before pre-shear 
Non-equilibrium minimum velocity	3,000E-4 rad/s
Zero strain at the start of each flow step	Yes
Inertia correction	No
Collect negative shear rate data if stress is positive	Yes
Collect all points	No
Display flow point graph during run	Yes
Store flow point graph with results	Yes
Store images to the results for flow steps	No
Creep zero displacement	Yes
Store images to the results for creep steps	No
Standard creep image store frequency	10 s
Repeated creep image store frequency in repeats	10 
Display oscillation waveform graph during run	Yes
Store oscillation waveform graph with results	Yes
Display strain control tries during run	Yes
Store strain control tries with results	Yes
Store images to the results for oscillation steps	No
Stress relaxation zero displacement	Yes
Store images to the results for stress relaxation steps	No
Flow torque limit	10,00 micro N.m
Flow velocity limit	1,000E-3 rad/s
Oscillation torque limit	5,00 micro N.m
Oscillation displacement limit	1,00E-5 rad
Oscillation raw phase limit	170,0 degrees
Oscillation minimum normal force limit	0 N
Oscillation maximum normal force limit	0 N
Flow velocity tolerance	5,00 %
Oscillation torque tolerance	1,00 %
Oscillation displacement tolerance	5,00 %
Oscillation velocity tolerance	5,00 %
Temperature tolerance	1,0 C

Stepped flow step 1

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

7,870E-4	9,687E-4	0,8125	9,9220	25,0	0
0,01761	2,154E-3	8,177	19,984	25,0	0
0,03214	4,638E-3	6,930	30,109	25,0	0
0,05631	9,993E-3	5,635	40,203	25,0	0

Stepped flow step 2

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,07937	9,998E-3	7,938	9,9840	25,0	0
0,1203	0,02155	5,583	20,062	25,0	0
0,1391	0,04642	2,997	30,156	25,0	0
0,1615	0,1000	1,615	40,219	25,0	0
0,1432	0,1000	1,432	50,265	25,0	0

Stepped flow step 3

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,1417	0,1000	1,417	9,9540	25,0	0
0,1465	0,1585	0,9246	20,016	25,0	0
0,1185	0,2512	0,4717	30,063	25,0	0
0,1468	0,3981	0,3688	40,157	25,0	0
0,1170	0,6310	0,1855	50,235	25,0	0
0,1030	1,000	0,1030	60,375	25,0	0

Stepped flow step 4

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,09823	1,000	0,09823	9,9060	25,0	0
0,1136	1,333	0,08515	19,922	25,0	0
0,1111	1,778	0,06246	30,078	25,0	0
0,1156	2,371	0,04876	40,188	25,0	0
0,1245	3,162	0,03938	50,313	25,0	0
0,1199	4,217	0,02844	60,438	25,0	0
0,1077	5,623	0,01915	70,516	25,0	0
0,1485	7,499	0,01981	80,656	25,0	0
0,1991	10,00	0,01991	90,719	25,0	0
0,3250	13,34	0,02437	100,73	25,0	0
0,4984	17,78	0,02803	110,80	25,0	0
0,7445	23,71	0,03140	120,89	25,0	0
1,138	31,62	0,03600	130,97	25,0	0
1,699	42,17	0,04028	141,08	25,0	0
2,777	56,23	0,04939	151,14	25,0	0
4,396	74,99	0,05862	161,22	25,0	0
6,570	100,0	0,06570	171,22	25,0	0

Temperature ramp step 1

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,2259	10,00	0,02259	9,0040	25,0	0
0,2243	10,00	0,02243	18,008	25,5	0
0,2227	10,00	0,02227	27,024	26,6	0
0,2192	10,00	0,02192	36,008	28,0	0
0,2174	10,00	0,02174	45,028	29,8	0
0,2143	10,00	0,02143	54,028	31,5	0
0,2200	10,00	0,02200	63,028	33,2	0
0,2097	10,00	0,02097	72,008	34,8	0
0,2079	10,00	0,02079	81,024	36,5	0
0,2061	10,00	0,02061	90,012	38,1	0
0,2037	10,00	0,02037	99,020	39,7	0
0,2026	10,00	0,02026	108,02	41,3	0
0,2047	10,00	0,02047	117,01	42,8	0
0,2036	10,00	0,02036	126,02	44,4	0
0,2070	10,00	0,02070	135,01	45,9	0
0,2064	10,00	0,02064	144,02	47,4	0
0,2093	10,00	0,02093	153,03	48,9	0
0,2097	10,00	0,02097	162,02	50,4	0
0,2116	10,00	0,02116	171,03	51,9	0
0,2151	10,00	0,02151	180,03	53,3	0
0,2190	10,00	0,02190	189,03	54,9	0
0,2236	10,00	0,02236	198,01	56,3	0
0,2285	10,00	0,02285	207,02	57,8	0
0,2338	10,00	0,02338	216,02	59,3	0
0,2396	10,00	0,02396	225,00	60,8	0
0,2493	10,00	0,02493	234,01	62,3	0
0,2592	10,00	0,02592	243,02	63,8	0
0,2714	10,00	0,02714	252,01	65,3	0
0,2816	10,00	0,02816	261,02	66,8	0
0,2966	10,00	0,02966	270,02	68,3	0
0,3124	10,00	0,03124	279,02	69,9	0
0,3365	10,00	0,03365	288,02	71,4	0
0,3668	10,00	0,03668	297,02	72,9	0
0,4254	9,999	0,04255	306,02	74,3	0
0,6495	10,00	0,06495	315,00	75,9	0
1,409	9,999	0,1409	324,01	77,5	0
3,013	9,999	0,3014	333,01	79,2	0
5,926	9,999	0,5926	342,02	80,8	0
9,459	10,00	0,9459	351,01	82,1	0
13,64	10,00	1,364	360,02	83,4	0
18,04	10,00	1,804	369,01	84,8	0

Temperature ramp step 2

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

22,53	10,00	2,253	9,0080	86,6	0
24,53	9,999	2,453	18,024	88,9	0
25,60	10,00	2,560	27,020	90,2	0
24,44	10,00	2,444	36,008	90,7	0
23,71	10,00	2,371	45,020	90,9	0
22,81	9,999	2,281	54,012	90,9	0
21,79	10,00	2,179	63,020	90,8	0
21,12	9,999	2,112	72,004	90,7	0
20,57	10,00	2,057	81,020	90,6	0
20,09	10,00	2,009	90,012	90,5	0
19,79	10,00	1,979	99,012	90,5	0
19,43	10,00	1,943	108,01	90,4	0
19,16	10,00	1,916	117,00	90,3	0
18,93	10,00	1,893	126,00	90,2	0
18,68	10,00	1,868	135,02	90,1	0
18,48	10,00	1,848	144,00	90,1	0
18,33	9,999	1,833	153,01	90,1	0
18,09	10,00	1,809	162,00	90,1	0
17,96	10,00	1,796	171,02	90,0	0
17,78	9,999	1,778	180,00	90,0	0
17,49	10,00	1,749	189,01	90,0	0
17,34	10,00	1,734	198,01	90,0	0
17,22	10,00	1,722	207,01	90,0	0
17,04	10,00	1,704	216,01	90,0	0
16,91	10,00	1,691	225,02	90,0	0
16,71	10,00	1,671	234,00	90,0	0
16,54	10,00	1,654	243,01	90,0	0
16,44	10,00	1,644	252,01	90,0	0
16,26	10,00	1,626	261,01	90,0	0
16,09	10,00	1,609	270,01	90,0	0
16,00	10,00	1,600	279,01	90,0	0

Temperature ramp step 3

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

15,77	9,999	1,577	9,0040	90,0	0
15,70	10,00	1,570	18,012	89,3	0
15,66	10,00	1,566	27,008	86,0	0
15,58	10,00	1,558	36,012	85,4	0
15,52	10,00	1,552	45,000	84,8	0
15,60	10,00	1,560	54,012	83,1	0
15,59	9,999	1,559	62,996	81,3	0
15,61	10,00	1,561	72,008	80,4	0
15,71	10,00	1,571	81,012	78,2	0
15,76	10,00	1,576	89,996	76,8	0
15,85	10,00	1,585	99,004	75,9	0
16,04	10,00	1,604	108,02	73,4	0
16,19	10,00	1,619	117,00	72,7	0
16,40	9,999	1,641	126,00	70,7	0
16,55	10,00	1,655	135,02	69,1	0
16,78	10,00	1,678	144,02	68,3	0
17,03	10,00	1,703	153,00	65,9	0
17,26	10,00	1,726	162,02	65,2	0
17,62	10,00	1,762	171,01	63,1	0
17,87	9,999	1,787	180,02	61,8	0
18,40	10,00	1,840	189,01	60,5	0
18,83	9,999	1,884	198,02	58,5	0
19,20	10,00	1,921	207,01	57,6	0
19,64	10,00	1,964	216,02	55,5	0
20,12	10,00	2,012	225,00	54,6	0
20,61	10,00	2,061	234,02	52,6	0
21,04	10,00	2,104	243,01	51,3	0
21,67	10,00	2,167	252,01	49,8	0
22,15	10,00	2,215	261,00	48,1	0
22,77	10,00	2,277	270,02	46,9	0
23,45	9,999	2,345	279,01	45,1	0
23,97	10,00	2,397	288,01	43,7	0
24,46	10,00	2,446	297,02	42,2	0
25,04	10,00	2,504	306,01	40,7	0
25,64	10,00	2,564	315,02	39,3	0
26,25	10,00	2,625	324,02	37,8	0
26,85	10,00	2,685	333,01	36,2	0
27,41	10,00	2,741	342,02	34,7	0
28,15	9,999	2,815	351,02	33,3	0
28,87	10,00	2,887	360,00	31,9	0
29,59	10,00	2,959	369,01	30,5	0

Stepped flow step 5

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,2727	9,939E-4	274,4	9,9540	25,0	0
0,7129	2,153E-3	331,1	20,016	25,0	0
1,352	4,640E-3	291,4	30,110	25,0	0
2,309	9,998E-3	231,0	40,172	25,0	0

Stepped flow step 6

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

2,819	9,999E-3	281,9	9,9840	25,0	0
4,061	0,02154	188,5	20,063	25,0	0
5,698	0,04641	122,8	30,141	25,0	0
7,654	0,1000	76,54	40,203	25,0	0
7,763	0,1000	77,63	50,281	25,0	0

Stepped flow step 7

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

7,776	0,1000	77,76	9,9690	25,0	0
9,115	0,1585	57,51	20,031	25,0	0
10,67	0,2512	42,49	30,063	25,0	0
12,70	0,3981	31,90	40,156	25,0	0
14,87	0,6310	23,57	50,172	25,0	0
17,74	1,000	17,74	60,266	25,0	0

Stepped flow step 8

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

17,40	1,000	17,40	9,9380	25,0	0
19,51	1,334	14,63	19,985	25,0	0
21,85	1,778	12,29	30,047	25,0	0
24,51	2,371	10,34	40,156	25,0	0
27,67	3,162	8,751	50,250	25,0	0
31,46	4,217	7,461	60,344	25,0	0
35,80	5,623	6,366	70,453	25,0	0
40,74	7,499	5,433	80,531	25,0	0
46,34	10,00	4,634	90,563	25,0	0
51,92	13,34	3,894	100,74	25,0	0
57,67	17,78	3,243	110,83	25,0	0
63,06	23,71	2,659	120,91	25,0	0
68,31	31,62	2,160	131,00	25,0	0
75,62	42,17	1,793	141,14	25,0	0
82,78	56,23	1,472	151,24	25,0	0
90,41	74,99	1,206	161,28	25,0	0
97,82	100,0	0,9782	171,39	25,0	0

